151224-49-6Relevant articles and documents
Convergent Paired Electrochemical Synthesis of Azoxy and Azo Compounds: An Insight into the Reaction Mechanism
Sadatnabi, Ali,Mohamadighader, Niloofar,Nematollahi, Davood
supporting information, p. 6488 - 6493 (2021/08/23)
A convergent paired electrochemical method was developed for the synthesis of azoxy and azo compounds starting from the corresponding nitroarenes. We propose a unique mechanism for electrosynthesis of azoxy and azo compounds. We find that both anodic and cathodic reactions are responsible for the synthesis of these compounds. The synthesis of azoxy and azo derivatives have been successfully performed in an undivided cell, using carbon rod electrodes, by constant current electrolysis at room temperature.
Behavior of organic compounds confined in monoliths of sol-gel silica glass. Effects of guest-host hydrogen bonding on uptake, release, and isomerization of the guest compounds
Badjic,Kostic
, p. 408 - 418 (2007/10/03)
Various proteins, catalysts, and other compounds can be encapsulated or diffused into porous sol-gel glasses, but little is known about their interactions with the glass matrix. We report unexpectedly large effects that hydrogen bonding between organic co
Effects of the Hydrogen-bonded Interactions on the Thermal cis to trans Isomerization of 3,3'-Diacetylazobenzene
Rosengaus, Jacqueline,Willner, Itamar
, p. 1044 - 1045 (2007/10/02)
The thermal isomerization of 3,3'-diacetyl-cis-azobenzene 1b is retarded in the presence of 2,4-bis(cyclohexylamino)-6-methoxy-1,3,5-triazine due to the formation of an intermolecular hydrogen-bonded assembly.