1513461-53-4Relevant academic research and scientific papers
From acetone metalation to the catalytic α-arylation of acyclic ketones with NHC-nickel(II) complexes
Henrion, Mickael,Chetcuti, Michael J.,Ritleng, Vincent
, p. 4624 - 4627 (2014)
Air-stable N-heterocyclic carbene-nickel(II) complexes at concentrations as low as 1 mol% exhibit high catalytic activity for the α-arylation of acyclic ketones and join a highly restricted list of nickel catalysts for this key reaction. Mechanistic investigations suggest a radical pathway. the Partner Organisations 2014.
