15146-22-2Relevant articles and documents
A heavy-metal-free desulfonylative Giese-type reaction of benzothiazole sulfones under visible-light conditions
Inuzuka, Toshiyasu,Iwama, Haruka,Ogawa, Daichi,Sengoku, Tetsuya,Yoda, Hidemi
, p. 9858 - 9861 (2021/10/12)
A visible-light-induced desulfonylative Giese-type reaction has been developed. Essential to the success is the employment of Hantzsch ester to activate benzothiazole sulfones without any heavy-metal additives. Not only benzylic benzothiazole sulfones but also alkyl ones were viable substrates and reacted with electron-deficient alkenes and a propiol amide.
Controlling factors for C-H functionalization versus cyclopropanation of dihydronaphthalenes
Nadeau, Etienne,Ventura, Dominic L.,Brekan, Jonathan A.,Davies, Huw M. L.
supporting information; experimental part, p. 1927 - 1939 (2010/06/17)
"Chemical Equation Presented" Rhodium(lI)-catalyzed reactions of vinyldiazoacetates with dihydronaphthalenes were systematically studied. These substrates underwent cyclopropanantion and/or the combined C-H activation/ Cope rearrangement in good overall y
Chemoselective rhodium-carbenoid reaction with the aromatic nucleus: An efficient methodology for 2-indanones, 2- Tetralones and 2-benzosuberones and its application in the synthesis of (±)-ar-Himachalene
Sudrik,Nanjundiah,Sonawane
, p. 1103 - 1112 (2007/10/03)
Rhodium-carbenoid species derived from rhodium acetate- catalyzed decomposition of aryl alkyl α- diazoke-tones have been shown to display a chemoselective addition into the aromatic nucleus, instead of insertion into an aliphatic C-H site. The synthetic u
Studies on Aromatic Sesquiterpenes. XIII. Synthesis of Lacinilene A and Its Structural Isomer
Tanaka, Juichi,Miyake, Takashi,Iwasaki, Noboru,Adachi, Kazuo
, p. 2851 - 2853 (2007/10/02)
Lacinilene A (6-norcadalen-7-ol) was synthesized from anisole through 6-norcalamenen-7-ol. 6-Nordaucalen-7-ol was also synthesized.
