151477-94-0

Basic information

• Product Name: Cyclopentanemethanol, 3-bromo-4-hydroxy-, (1-alpha-,3-ba-,4-alpha-)- (9CI)
• Synonyms: Cyclopentanemethanol,3-bromo-4-hydroxy-,(1-alpha-,3-bta-,4-alpha-)-(9CI);Cyclopentanemethanol, 3-bromo-4-hydroxy-, (1-alpha-,3-ba-,4-alpha-)- (9CI);Cyclopentanemethanol, 3-bromo-4-hydroxy-, (1-alpha-,3-b
• CAS NO: 151477-94-0
• Molecular Formula: C6H11BrO2
• Molecular Weight: 195.05434
• Product Categories: CYCLOPENTANE
• Mol File: 151477-94-0.mol
• Article Data: 2

Chemical Properties

• Appearance: /
• CAS DataBase Reference: Cyclopentanemethanol, 3-bromo-4-hydroxy-, (1-alpha-,3-ba-,4-alpha-)- (9CI)(CAS DataBase Reference)
• NIST Chemistry Reference: Cyclopentanemethanol, 3-bromo-4-hydroxy-, (1-alpha-,3-ba-,4-alpha-)- (9CI)(151477-94-0)
• EPA Substance Registry System: Cyclopentanemethanol, 3-bromo-4-hydroxy-, (1-alpha-,3-ba-,4-alpha-)- (9CI)(151477-94-0)

Safety Data

• Hazardous Substances Data: 151477-94-0(Hazardous Substances Data)

Upstream product

• 7686-77-3 3-cyclopentene-1-carboxylic acid 
• 130505-94-1 (1RS,4SR,6RS)-6-bromo-2-oxabicyclo<2.2.1>heptan-3-one 

Downstream Products

• 118237-87-9 cis-(+/-)-2-Amino-6-chloro-9-<4-(hydroxymethyl)-2-cyclopenten-1-yl>-9H-purine 

Relevant articles and documents

Concise Racemic and Highly Enantioselective Approaches to Key Intermediates for the Syntheses of Carbocyclic Nucleosides and pseudo-Ribofuranoses: Formal Syntheses of Carbovir

A regio- and stereo-specific synthesis of cis-(+/-)-3-acetoxy-5-(acetoxymethyl)cyclopentene 3 from cyclopent-3-enecarboxylic acid 4 via a bromolactonisation strategy is described.Pd-catalysed coupling of the cis-(+/-)-diacetate 3 with 2-amino-6-chloropurine or 2,6-diaminopurine leads to the formal syntheses of carbovir 1.A synthesis of the (1R)-cis-diacetate 15 (R = Ac) is described via a highly enantioselective rearrangement of cis-6-oxabicyclohexane-3-methanol 13 (also prepared from the acid 4) using the dilithium salt of (1S,2R)-norephedrine.