151503-39-8Relevant academic research and scientific papers
Cascade palladium-catalyzed direct intramolecular arylation/alkene isomerization sequences: Synthesis of indoles and benzofurans
Yagoubi, Myriam,Cruz, Ana C. F.,Nichols, Paula L.,Elliott, Richard L.,Willis, Michael C.
supporting information; experimental part, p. 7958 - 7962 (2011/01/11)
One route, two cycles: A palladium-catalyzed intramolecular direct arylation reaction combined with an isomerization step provided a straightforward synthetic route to both indoles and benzofurans (see scheme). Isolation and functionalization of intermedi
The influence of the 5-methyl group in bacteriorhodopsin
Groesbeeck, M.,Vries, E. F. J. de,Berden, J. A.,Lugtenburg, J.
, p. 303 - 308 (2007/10/02)
All-E-5-bromo-5-demethylretinal was prepared in 6percent yield starting from 4,4-dimethyl-2-cyclohexenone via 2-bromo-6,6-dimethyl-1-cyclohexenecarboxaldehyde.The crucial step in the preparation of the intermediate is a 2,3 Wittig rearrangement. 5-Bromo-5
