151515-23-0Relevant articles and documents
Indirect Access to Carbene Adducts of Bismuth- And Antimony-Substituted Phosphaketene and Their Unusual Thermal Transformation to Dipnictines and [(NHC)2OCP][OCP]
Walley, Jacob E.,Warring, Levi S.,Kertész, Erik,Wang, Guocang,Dickie, Diane A.,Benk?, Zoltán,Gilliard, Robert J.
, p. 4733 - 4743 (2021)
The synthesis and thermal redox chemistry of the first antimony (Sb)- and bismuth (Bi)-phosphaketene adducts are described. When diphenylpnictogen chloride [Ph2PnCl (Pn = Sb or Bi)] is reacted with sodium 2-phosphaethynolate [Na[OCP]·(dioxane)x], tetraphe
Stabilization of a transient diorganogermylene by an N-heterocyclic carbene
Rupar, Paul A.,Jennings, Michael C.,Ragogna, Paul J.,Baines, Kim M.
, p. 4109 - 4111 (2008/10/09)
The synthesis of a carbene-stabilized transient germylene is presented; the resulting complex liberates free germylene upon heating, forms a stable adduct with BH3, and reacts with MeLi to displace the carbene.