151601-12-6

Basic information

• Product Name: [1,1-Biphenyl]-2,2,4-triol,5-methoxy-(9CI)
• Synonyms: [1,1-Biphenyl]-2,2,4-triol,5-methoxy-(9CI)
• CAS NO: 151601-12-6
• Molecular Formula: C13H12O4
• Molecular Weight: 232.23198
• Product Categories: BIPHENYL
• Mol File: 151601-12-6.mol
• Article Data: 4

Chemical Properties

• Appearance: /
• CAS DataBase Reference: [1,1-Biphenyl]-2,2,4-triol,5-methoxy-(9CI)(CAS DataBase Reference)
• NIST Chemistry Reference: [1,1-Biphenyl]-2,2,4-triol,5-methoxy-(9CI)(151601-12-6)
• EPA Substance Registry System: [1,1-Biphenyl]-2,2,4-triol,5-methoxy-(9CI)(151601-12-6)

Safety Data

• Hazardous Substances Data: 151601-12-6(Hazardous Substances Data)

Usage

Synthesis Reference(s)

The Journal of Organic Chemistry, 58, p. 7271, 1993 DOI: 10.1021/jo00077a059

Upstream product

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Relevant articles and documents

Selective Synthesis of Unsymmetrical Hydroxylated and Methoxylated Biaryls

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Efficient Coupling Reaction of Quinone Monoacetal with Phenols Leading to Phenol Biaryls

A simple and efficient synthesis of phenol biaryls by the cross-couplings of quinone monoacetals (QMAs) and phenols is reported. The Br?nsted acid catalytic system in 1,1,1,3,3,3-hexafluoro-2-propanol was found to be particularly efficient for this transformation. This reaction can be extended to the synthesis of various phenol biaryls, including sterically hindered biaryls, with yields ranging from 58 to 90 % under mild reaction conditions and in a highly regiospecific manner.