151670-03-0

Upstream product

• 23558-05-6 3-O-benzyl-1,2-O-isopropylidene-1,5-D-xylo-dialdofuranose 
• 37776-17-3 5,6-anhydro-3-O-benzyl-1,2-O-isopropylidene-β-L-idofuranose 
• 220051-35-4 (3aR,5R,6S,6aR)-6-Benzyloxy-2,2-dimethyl-5-(S)-oxetan-2-yl-tetrahydro-furo[2,3-d][1,3]dioxole 
• 220098-13-5 Acetic acid (S)-3-acetoxy-1-((3aR,5R,6S,6aR)-6-benzyloxy-2,2-dimethyl-tetrahydro-furo[2,3-d][1,3]dioxol-5-yl)-propyl ester 
• 151670-12-1 methyl 3-O-benzyl-6-deoxy-1,2-O-isopropylidene-β-L-ido-heptofuranuronate 

Relevant academic research and scientific papers

Synthesis of 6-deoxyheptose derivatives via cyclic sulfates and oxetanes

Two approaches for the chain elongation and synthesis of 6-deoxyheptose derivatives are described. The first one is based on the regioselective ring opening of 4,6-cyclic sulfate glycopyranoside derivatives at carbon 6 by cyanide ion. The second approach involves the ring expansion of 5,6-anhydro to 5,7-anhydro sugars and subsequent opening of the resulting oxetane, derivative using acetate ion as nucleophile.

The Raction of Acetyliron 5-C5H5)Fe(CO)(PPh3)(COCH3)> with Sugar Aldehydes. New Synthesis of Deoxysugars

Aldol reactions of sugar aldehydes (5-13) with enolate 2 of racemic and both enantiomeric forms of acetyliron were investigated.The steric course of reactions depended strongly on the counterions used.High stereocontrol was achieved with the following cat