151710-75-7Relevant academic research and scientific papers
Stereoselective synthesis of E,Z-configured 1,3-dienes by ring-closing metathesis. Application to the total synthesis of lactimidomycin
Gallenkamp, Daniel,Fuerstner, Alois
, p. 9232 - 9235 (2011/08/06)
Strategic positioning of a silyl group on the diene unit of a diene-ene substrate allows rigorous regio- and stereocontrol to be exerted during metathesis-based macrocyclization reactions. The versatility of this concise approach to E,Z-configured 1,3-die
Synthesis of Silicon Substituted Cyclopropylmethyl Alcohols in Optically Active Form via Asymmetric Simmons-Smith Reaction of γ-Silicon Substituted Allylic Alcohols
Ukaji, Yutaka,Sada, Kazunori,Inomata, Katsuhiko
, p. 1227 - 1230 (2007/10/02)
Optically active silicon substituted cyclopropyl methyl alcohols were synthesized through asymmetric Simmons-Smith reaction; that is, the reaction of γ-silicon substituted allylic alcohols with diethylzinc and diiodomethane utilizing (+)-diethyl tartrate
