15181-47-2Relevant academic research and scientific papers
Side-on versus end-on bonding of O2 to the FSO3 radical: Matrix isolation and ab initio study of FSO5
Beckers, Helmut,Garcia, Placido,Willner, Helge,Argueello, Gustavo A.,Cobos, Carlos J.,Francisco, Joseph S.
, p. 3754 - 3757 (2008/02/12)
(Figure Presented) Quantum-chemical calculations predict the existence of two almost equal-energy isomers of the FSO5 radical with either side-on or end-on bonding of O2 to FSO3 (see picture). The structure of this polyoxy radical isolated in solid noble-gas matrices and formed by the reaction of FSO3 with molecular oxygen has now been revealed by IR and UV spectroscopic investigations.
