151872-43-4Relevant articles and documents
Reaction of C60 with Inactive Secondary Amines and Aldehydes and the Cu(OAc)2-Promoted Regioselective Intramolecular C-H Functionalization of the Generated Fulleropyrrolidines
Yang, Hai-Tao,Tan, Yi-Chen,Ge, Jie,Wu, He,Li, Jia-Xing,Yang, Yang,Sun, Xiao-Qiang,Miao, Chun-Bao
, p. 11201 - 11209 (2016/11/28)
The thermal reaction of C60 with aromatic aldehydes and inactive secondary amines for the stereoselective synthesis of trans-1,2,5-trisubstituted fulleropyrrolidines has been developed. Moreover, when an o-hydroxyl group was located at the phenyl ring of the generated fulleropyrrolidines, the Cu(OAc)2-promoted regioselective intramolecular C-O coupling reaction occurred to generate unique tricycle-fused fullerene derivatives.