1520075-41-5Relevant academic research and scientific papers
Ligand-free PdCl2-catalyzed heck reaction of arylboronic acids and olefins under reusable TBAB/H2O conditions
Tang, Bo-Xiao,Fang, Xiao-Niu,Kuang, Ren-Yun,Hu, Rong-Hua,Wang, Ji-Wei,Li, Ping,Li, Xiao-Hang
, p. 2971 - 2976 (2013/11/06)
A novel method was developed for Heck reaction of olefins and arylboronic acids using a ligand-free PdCl2 catalyst to afford the coupling products with excellent regio- and stereoselectivity. It is noteworthy that the PdCl2/CuSO4/K2CO3/TBAB/H 2O system can be recovered and used for three cycles directly. Georg Thieme Verlag Stuttgart, New York.
