152035-75-1Relevant academic research and scientific papers
Synthesis and Revised Structure of Garuganin III
Keserue, Gyoergy M.,Dienes, Zoltan,Nogradi, Mihaly,Kajtar-Peredy, Maria
, p. 6725 - 6728 (2007/10/02)
Macrocyclic β-methoxy enones 6 and 1-3, i.e., garuganin III and its constitutional and stereoisomers, were synthesized using an isoxazole synthon for the introduction of the β-methoxy enone function.Ring closure was accomplished by an intramolecular Wittig reaction.Compound 6 rather than 1, as suggested previously, was found to have an 1H-NMR spectrum and a mp identical to those of garuganin III.
