1521246-82-1Relevant academic research and scientific papers
First P,P bidentate phosphine-phosphite-type ligand with a Pstereocenter in the phosphite moiety: Synthesis and application in the Pd-catalyzed asymmetric allylic alkylation
Gavrilov,Zheglov,Shiryaev,Potapova,Gavrilov,Volov,Zamilatskov
, p. 1097 - 1102 (2013)
A new P,P bidentate phosphine-diamidophosphite bearing an asymmetric phosphorus atom in the 1,3,2-diazaphospholidine ring was obtained. A possibility of its application in the palladium-catalyzed enantioselective allylic substitution was demonstrated. A 70% ee was reached in the alkylation of (E)-1,3-diphenylallyl acetate with dimethyl malonate.
