152125-34-3

Upstream product

• 152187-07-0 Methyl (3R,E)-3-(4-tert-Butyldimethylsilyloxy-2,6,6-trimethylcyclohex-1-enyl)prop-2-enoate 
• 20548-02-1 (4R,6R)-4-hydroxy-2,2,6-trimethylcyclohexan-1-one 
• 130583-95-8 (4R,6R)-4-[(tert-butyldimethylsilyl)oxy]-2,2,6-trimethylcyclohexan-1-one 
• 152187-06-9 (R)-5-(tert-butyldimethylsilyloxy)-2-[(trifluoromethanesulfonyl)oxy]-1,3,3-trimethylcyclohex-1-ene 

Downstream Products

• 214335-78-1 (E)-3-((R)-4-Acetoxy-2,6,6-trimethyl-cyclohex-1-enyl)-acrylic acid methyl ester 

Relevant academic research and scientific papers

Carotenoids and related polyenes. Part 5. Lewis acid-promoted stereoselective rearrangement of 5,6-epoxy carotenoid model compounds

The novel acyclic tetrasubstituted olefinic end group and the cyclopentyl end group of carotenoids were obtained by Lewis acid-promoted stereoselective rearrangement of the epoxide end group of 5,6-epoxy carotenoids. The scope and limitation of this rearr

First Total Synthesis of (+/-)-Peridinin, (+/-)-Pyrrhoxanthin and the Optically Active Peridinin

The first total synthesis of peridinin 1 and pyrrhoxanthin 2 has been accomplished via the reaction of the C15-epoxy formyl ester 21 with the C22-allenic sulfone 28 or the C22-acetylenic sulfone 39.A synthesis of the optically active peridinin has also be