152187-10-5

Upstream product

• 152187-06-9 (R)-5-(tert-butyldimethylsilyloxy)-2-[(trifluoromethanesulfonyl)oxy]-1,3,3-trimethylcyclohex-1-ene 
• 152187-07-0 Methyl (3R,E)-3-(4-tert-Butyldimethylsilyloxy-2,6,6-trimethylcyclohex-1-enyl)prop-2-enoate 
• 18162-48-6 tert-butyldimethylsilyl chloride 
• 130583-95-8 (4R,6R)-4-[(tert-butyldimethylsilyl)oxy]-2,2,6-trimethylcyclohexan-1-one 
• 20548-02-1 (4R,6R)-4-hydroxy-2,2,6-trimethylcyclohexan-1-one 
• 108-24-7 acetic anhydride 
• 83021-09-4 (-)-3-<(R)-4-(t-Butyl)dimethylsilyloxy-2,6,6-trimethyl-1-cyclohexen-1-yl>propen-1-ol 

Downstream Products

• 152187-11-6 (E)-<3-(4-tert-Butyldimethylsilyloxy-2,6,6-trimethylcyclohex-1-enyl)allyl>sulfonylbenzene 
• 152187-13-8 (2Z,4E)-5-(4-Hydroxy-2,6,6-trimethylcyclohex-1-enyl)-3-methoxycarbonylpenta-2,4-dienal 

Relevant academic research and scientific papers

Versatile amine-promoted mild methanolysis of 3,5-dinitrobenzoates and its application to the synthesis of Colorado potato beetle pheromone

A mild deacylation method for 3,5-dinitrobenzoates using methanolic solutions of amines, such as dialkylamines, was developed. The method’s versatility was confirmed by applying it to synthesizing a key intermediate for Colorado potato beetle pheromone.

First Total Synthesis of (+/-)-Peridinin, (+/-)-Pyrrhoxanthin and the Optically Active Peridinin

The first total synthesis of peridinin 1 and pyrrhoxanthin 2 has been accomplished via the reaction of the C15-epoxy formyl ester 21 with the C22-allenic sulfone 28 or the C22-acetylenic sulfone 39.A synthesis of the optically active peridinin has also be