152190-08-4

Basic information

• Product Name: (4-Methoxy-2-methyl-phenyl)-((R)-1-phenyl-ethyl)-amine
• CAS NO: 152190-08-4
• Molecular Weight: 241.333
• Mol File: 152190-08-4.mol

Chemical Properties

• CAS DataBase Reference: (4-Methoxy-2-methyl-phenyl)-((R)-1-phenyl-ethyl)-amine(CAS DataBase Reference)
• NIST Chemistry Reference: (4-Methoxy-2-methyl-phenyl)-((R)-1-phenyl-ethyl)-amine(152190-08-4)
• EPA Substance Registry System: (4-Methoxy-2-methyl-phenyl)-((R)-1-phenyl-ethyl)-amine(152190-08-4)

Safety Data

• Hazardous Substances Data: 152190-08-4(Hazardous Substances Data)

Upstream product

• 917-54-4 methyllithium 
• 152190-17-5 (4-Methoxy-2-methyl-phenyl)-[1-phenyl-meth-(E)-ylidene]-amine 

Relevant articles and documents

Asymmetric 1,2-Addition of Organolithiums to Aldimines Catalyzed by Chiral Ligand

An asymmetric 1,2-addition reaction of organolithiums with imines 3, 7 was catalyzed by a 0.05-1.3 equivalent of a chiral amino ether 2 to provide the corresponding optically active amines 4, 8.

Steric tuning in chiral ligand mediated enantioselective alkylation of imines

Enantioselective alkylation of achiral aldimines 4 prepared from 2-methylanisidine with organolithiums was mediated by a chiral aminoether 1 to give the corresponding amines 5 in high ee.