152193-53-8Relevant academic research and scientific papers
Synthesis, Characterisation and Structure of Square-planar Palladium(II) Complexes with Phosphine-Pyridine Hybrid Ligands o-Ph2PC6H4CH2O(CH2)nC5H4N-2 (n = 1-3). Isolation of the First Transition-metal Complex with a trans-Chelating Bidentate PN Ligand
Tani, Kazuhide,Yabuta, Masami,Nakamura, Shingo,Yamagata, Tsuneaki
, p. 2781 - 2790 (2007/10/02)
The reaction of Na2 or with an equimolar amount of new bidentate hybrid ligands having a P and a N donor atom capable of trans chelation, o-Ph2PC6H4CH2O(CH2)nC5H4N-2 (n = 1-3), gave mainly the 1:1 complex PdCl2o-Ph2PC6H4CH2O(CH2)nC
Synthesis and Molecular Structure of trans-PdCl2. The First Transition Metal Complex Containing trans Coordinating Bidentate Pyridyl-phospine Ligand
Yabuta, Masami,Nakamura, Shingo,Yamagata, Tsuneaki,Tani, Kazuhide
, p. 323 - 326 (2007/10/02)
As the first example of a crystallographically confirmed transition metal complex with a bidentate hybrid ligand spanning trans positions, the square-planar palladium(II) complex containing the trans chelating pyridyl-phosphine bidentate hybrid ligand, bound through a pyridine and a phosphine, trans-PdCl2, is prepared and the crystal structure was determined.
