152202-85-2Relevant academic research and scientific papers
Convergent synthesis of passifloricin a via a prins cyclisation and olefin cross-metathesis approach
Sabitha, Gowravaram,Prasad, Muddala Nagendra,Shankaraiah, Konatham,Reddy, Nandyala Mallikarjuna,Yadav, Jhillu Singh
experimental part, p. 3891 - 3898 (2010/12/25)
A stereoselective and convergent approach to the total synthesis of the natural product passifloricin A is illustrated using Prins cyclisation and metathesis reactions as key steps. Georg Thieme Verlag Stuttgart · New York.
Synthesis of Acyclic Polyol Derivatives via Enzyme-Mediated Aldol Reaction
Matsumoto, Kazutsugu,Shimagaki, Masayuki,Nakata, Tadashi,Oishi, Takeshi
, p. 4935 - 4938 (2007/10/02)
Enzyme-mediated stereoselective aldol reaction between dihydroxyacetone phosphate (DHAP, 1) and (2R,4R)-6-benzyloxy-2,4-dimethoxyhexanal (8) was catalyzed by rabbit muscle aldolase (RAMA) to generate (3S,4R,5R,7R)-trihydroxyketone 12, which could be easily transformed to the masked polyhydroxylated compound 15 corresponding to the C-9-C-16 segment of pentamycin (6).
