152203-02-6

Basic information

• Product Name: Methyl 4-O-(5a-carba-α-D-glucopyranosyl)-α-D-glucopyranoside
• Synonyms: Methyl 4-O-(5a-carba-α-D-glucopyranosyl)-α-D-glucopyranoside
• CAS NO: 152203-02-6
• Molecular Weight: 354.354
• Mol File: 152203-02-6.mol

Chemical Properties

• CAS DataBase Reference: Methyl 4-O-(5a-carba-α-D-glucopyranosyl)-α-D-glucopyranoside(CAS DataBase Reference)
• NIST Chemistry Reference: Methyl 4-O-(5a-carba-α-D-glucopyranosyl)-α-D-glucopyranoside(152203-02-6)
• EPA Substance Registry System: Methyl 4-O-(5a-carba-α-D-glucopyranosyl)-α-D-glucopyranoside(152203-02-6)

Safety Data

• Hazardous Substances Data: 152203-02-6(Hazardous Substances Data)

Upstream product

• 152038-15-8 Methyl 2,3,6-tri-O-benzyl-4-O-(3,4,6-tri-O-benzyl-5a-carba-α-D-mannopyranosyl)-α-D-glucopyranoside 
• 152203-03-7 (1R,2R,3S,4R,5R)-1,2-anhydro-3,4-di-O-benzyl-5-benzyloxymethylcyclohexan-1,2,3,4-tetraol 
• 19488-48-3 methyl O-2,3,6-tri-O-benzyl-α-D-glucopyranoside 
• 152203-04-8 Methyl 2,3,6-tri-O-benzyl-4-O-(3,4,6-tri-O-benzyl-5a-carba-α-D-glucopyranosyl)-α-D-glucopyranoside 
• 152203-05-9 Methyl 4-O-(2-O-acetyl-3,4,6-tri-O-benzyl-5a-carba-α-D-glucopyranosyl)-2,3,6-tri-O-benzyl-α-D-glucopyranoside 

Relevant articles and documents

Pseudosugars, 36: Synthesis of methyl 5a′-carbamaltoses linked by imino, ether and sulfide bridges and unsaturated derivatives thereof

Methyl 5a′-carbamaltoses linked by imino, ether, and sulfide bridges were synthesized by coupling of an amino carbasugar with a sugar epoxide and of the carbasugar epoxide with the oxide anion or thioacetate derived from sugar derivatives. Their unsaturated derivatives related to a potent α-glucosidase inhibitor, methyl acarviosin, were also synthesized. Moderate inhibitory activity against baker's yeast α-glucosidase was observed only for the imino-linked compounds 2 and 5. VCH Verlagsgesellschaft mbH, 1996.

Convenient Synthesis of Oxo-Linked 5a-Carba-di- and tri-saccharides of Biological Interests

Some oxo-linked 5a-carba-di and tri-saccharides of biological interests, including 5a-carbamaltose, were synthesized by coupling of 5a-carba-glycosyl donor, 1,2-anhydro-5a-carba-β-D-mannopyranose derivative with the alkoxides generated from the protected