152236-07-2Relevant articles and documents
Fritsch-Wiechell Rearrangement of 1-Chlorovinyl Sulfoxides: A New Method for Synthesizing Acetylenes from Aldehydes with One-Carbon Homologation
Satoh, Tsuyoshi,Hayashi, Yasumasa,Yamakawa, Koji
, p. 1866 - 1869 (2007/10/02)
1-Chlorovinyl sulfoxides, easily prepared from aldehydes and chloromethyl phenyl sulfoxides, were treated with t-butyllithium to afford one-carbon homologated acetylenes via alkylidene carbenoids in high yields.