152291-69-5

Upstream product

• 21524-34-5 2,4,6-triisopropyl-1-bromobenzene 
• 115160-05-9 1-bromo-2,4,6-tris[bis(trimethylsilyl)methyl]benzene 
• 74226-59-8 2,4,6-triisopropylphenyl lithium 
• 125444-10-2 {2,4,6-tris-(bis-(trimethylsilyl)methyl)phenyl}lithium 

Downstream Products

• 152291-64-0 5-(2,4,6-tris(bis(trimethylsilyl)methyl)phenyl)-5-(2,4,6-triisopropylphenyl)-1,2,3,4,5-tetrathiagermolane 
• 153289-23-7 2-(2,4,6-tris(bis(trimethylsilyl)methyl)phenyl)-2-(2,4,6-triisopropylphenyl)-4,5-diphenyl-3,4-dioxagerma-3-cyclopentene 
• 152291-63-9 [2,4,6-tris[bis(trimethylsilyl)methyl]phenyl](2,4,6-triisopropylphenyl)germanethione 
• 247245-84-7 2-[2,4,6-tris[bis(trimethylsilyl)methyl]phenyl]-2-(2,4,6-triisopropylphenyl)-4,6,6-trimethyl-1-thia-2-germacyclohex-4-ene 
• 247245-87-0 2-[2,4,6-tris[bis(trimethylsilyl)methyl]phenyl]-2-(2,4,6-triisopropylphenyl)-5-methyl-1-selena-2-germacyclohex-4-ene 
• 247245-85-8 2-[2,4,6-tris[bis(trimethylsilyl)-methyl]phenyl]-2-(2,4,6-triisopropylphenyl)-4-methyl-1-selena-2-germacyclohex-4-ene 
• 220879-98-1 2-[2,4,6-tris[bis(trimethylsilyl)methyl]phenyl]-2-(2,4,6-triisopropylphenyl)-4-methyl-1-thia-2-germacyclohex-4-ene 
• 152291-65-1 [2,4,6-tris[bis(trimethylsilyl)methyl]phenyl](hydroxy)(2,4,6-triisopropylphenyl)(mercapto)germane 
• 247245-81-4 [2,4,6-tris[bis(trimethylsilyl)methyl]phenyl](2,4,6-triisopropylphenyl)(mercapto)(methyl)germane 
• 163273-59-4 2-[2,4,6-tris[bis(trimethylsilyl)methyl]phenyl]-2-(2,4,6-triisopropylphenyl)-4-mesityl-1,3,5,2-oxaselenazagermole 
• 163273-58-3 2-[2,4,6-tris[bis(trimethylsilyl)methyl]phenyl]-2-(2,4,6-triisopropylphenyl)-4,5-dimethyl-1-selena-2-germacyclohex-4-ene 
• 163273-57-2 [2,4,6-tris[bis(trimethylsilyl)methyl]phenyl](2,4,6-triisopropylphenyl)germaneselone 
• 152291-66-2 ((((CH₃)3Si)2CH)3C₆H₂)(((CH₃)2CH)3C₆H₂)(GeSC₄H₄)(CH₃)2 
• 152291-67-3 ((((CH₃)3Si)2CH)3C₆H₂)(((CH₃)2CH)3C₆H₂)(GeSONC)((C₆H₂)(CH₃)3) 

Relevant academic research and scientific papers

Synthesis and crystal structure of the first base-free diarylgermylene-transition metal mononuclear complexes

The first base-free diarylgermylene-transition metal mononuclear complexes Tb(Tip)Ge=M-(CO)5 (1, M = W; 2, M = Cr; Tb = 2,4,6-tris[bis(trimethylsilyl)methyl]phenyl, Tip = 2,4,6-triisopropylphenyl) were synthesized by the reaction of a new type of kinetically stabilized diarylgermylene Tb(Tip)Ge: (3), obtained by the treatment of germanium(II) iodide with bulky aryllithiums (TbLi and TipLi), with the corresponding pentacarbonylmetal(0)-tetrahydrofuran complexes of group 6 metals (W and Cr). Of the two diarylgermylene-group 6 metal complexes (1 and 2), the molecular structure of 1 was determined by X-ray crystallographic analysis. Crystal data with Mo Ka radiation (λ = 0.710 69 A?): 1, C47H82GeO5Si6W, triclinic, space group P1, a = 12.490(2) A?, b = 23.890(3) A?, c = 10.254(1) A?, α = 96.21(1)°, β = 105.52(1)°, γ = 89.82(1)°, V = 2930(1) A?3, Z = 2, R = 0.045, Rw = 0.045 based on 8032 reflections with I > 3σ(I) together with 541 variable parameters.