152330-18-2Relevant academic research and scientific papers
Chemoselective introduction of acetylene into hindered carbonyl group using alkynyltrifluoroborate, a solution as one step to (-)-tetrodotoxin
Yamamoto, Noboru,Isobe, Minoru
, p. 6581 - 6590 (2007/10/02)
Optically active cyclohexane moiety precursor for tetrodotoxin molecule was synthesized by Diels-Alder cycloaddition between a bromo derivative of levoglucosenone and Danishefsky type diene. The unstable product, bromo-ketone, was converted into vinylphos
