152340-08-4Relevant articles and documents
Syntheses and Structures of Six-Membered Cyclometallaphosphanes Containing Tellurium(IV) and Rhenium(VII)
Leictweis, Iring,Hasselbring, Reinhard,Roesky, Herbert W.,Noltemeyer, Mathias,Herzog, Axel
, p. 1234 - 1240 (2007/10/02)
The reactions of the tridentate ligands (Me3Si)2NC(4-RC6H4)NPPh2NSiMe3 with Re2O7 yield the six-membered rings .The acyclic compound Me3SiNC(4-CF3C6H4)NPPh2NReO2OSiMe3 (5) has been obtained by reaction of 2 with Me3SiOReO3. 2 reacts quantitatively with TeCl4 to form the metallacycle *pyridine (6)*pyridine.The molecular structures of 4*CH2Cl2 and 6*pyridine*0.5 toluene have been determined by X-ray diffraction.