15237-64-6Relevant academic research and scientific papers
Preparation of NHC borane complexes by lewis base exchange with amine- and phosphine-boranes
Brahmi, Malika Makhlouf,Monot, Julien,Desage-El Murr, Marine,Curran, Dennis P.,Fensterbank, Louis,Lacote, Emmanuel,Malacria, Max
supporting information; experimental part, p. 6983 - 6985 (2010/11/24)
A versatile new method for the preparation of NHC boranes starting from two stable, readily available reactants-an heterocyclic salt and an amine or phosphine-borane-is reported. It uses a Lewis base exchange at boron and provides easy access to new NHC boranes, in particular B-substituted borane ones.
THE REACTIONS OF DIBORANE WITH ARYL-ORGANOTIN COMPOUNDS
Pickles, G. M.,Spencer, T.,Thorpe, F. G.,Chopa, A. B.,Podesta, J. C.
, p. 7 - 16 (2007/10/02)
A number of tetraaryltin compounds, Ar4Sn (where Ar = phenyl, o- and p-tolyl, and p-chlorophenyl) and tryphenyltin compounds, PH3SnX (where X = Cl, H, OH, OCOCH3 and OCOCF3) have been treated with diborane in tetrahydrofuran.Transmetallation occurs in which one or more aryl groups are transferred to boron.The organoboron intermediates give phenols upon oxidation and boronic and borinic acids upon hydrolysis.Pyridine complexes of organoboranes have also been isolated.
