1524-26-1

Basic information

• Product Name: 1,1,1-TRIFLUOROBUTENE-3
• Synonyms: 1,1,1-TRIFLUOROBUTENE-3;4,4,4-TRIFLUORO-1-BUTENE;4,4,4-Trifluoro-1-butene 97%;4,4,4-Trifluoro-1-butene97%;3-(Trifluoromethyl)prop-1-ene;4,4,4-Trifluorobut-1-ene 97%;1,1,1,trifluorobut-3-ene;4,4,4-Trifluorobut-1-ene97%
• CAS NO: 1524-26-1
• Molecular Formula: C₄H₅F₃
• Molecular Weight: 110.08
• Mol File: 1524-26-1.mol
• Article Data: 14

Chemical Properties

• Boiling Point: 11
• Flash Point: °C
• Appearance: /
• Density: 1.038g/cm³
• CAS DataBase Reference: 1,1,1-TRIFLUOROBUTENE-3(CAS DataBase Reference)
• NIST Chemistry Reference: 1,1,1-TRIFLUOROBUTENE-3(1524-26-1)
• EPA Substance Registry System: 1,1,1-TRIFLUOROBUTENE-3(1524-26-1)

Safety Data

• Hazardous Substances Data: 1524-26-1(Hazardous Substances Data)

Usage

Synthesis Reference(s)

Journal of the American Chemical Society, 107, p. 5014, 1985 DOI: 10.1021/ja00303a042

Upstream product

• 406-85-9 1-chloro-4,4,4-trifluorobutane 
• 406-72-4 4-chloro-1,1,1-trifluoro-3-iodo-butane 
• 187737-37-7 propene 
• 2314-97-8 iodotrifluoromethane 
• 118337-48-7 allyl chlorodifluoroacetate 
• 1514-87-0 metyhyl chlorodifluoroacetate 
• 106-95-6 allyl bromide 
• 680-15-9 2,2-difluoro-2-(fluorosulfonyl)acetate 
• 88986-32-7 methyl 3-oxa-ω-fluorosulfonylperfluoropentanoate 
• 113591-64-3 allyl fluorosulfonyldifluoroacetate 
• 540-87-4 3-iodo-1,1,1-trifluorobutane 
• 2264-21-3 trifluoromethyl radical 
• 556-56-9 allyl iodid 
• 461-17-6 1,1,1-trifluoro-4-iodo-butane 

Downstream Products

• 406-87-1 4,4,4-trifluorobutanal 
• 2366-70-3 4,4,4-trifluorobutan-2-one 

Relevant articles and documents

A FACILE PREPARATION OF 1-PERFLUOROALKYLALKENES AND ALKYNES. PALLADIUM CATALYZED REACTION OF PERFLUOROALKYL IODIDES WITH ORGANOTIN COMPOUNDS

Alkenyl, allyl, and alkynylstannanes react with perfluoroalkyl iodides in the presence of a catalytic amount of Pd(PPh3)4 to give alkenes and alkynes bearing perfluoroalkyl group.

METHYL CHLORODIFLUOROACETATE. A CONVENIENT TRIFLUOROMETHYLATING AGENT

Treatment of methyl chlorodifluoroacetate with organic halides in the presence of KF and CuI at 100-120 deg C for 7-8 h in DMF gave the corresponding trifluoromethylated derivatives in moderate to high yields.

METHYL CHLORODIFLUOROACETATE - A CONVENIENT TRIFLUOROMETHYLATING AGENT

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METHOD FOR PRODUCING FLUORINE-CONTAINING ALCOHOL

PROBLEM TO BE SOLVED: To provide a method for the production of a fluorine-containing alcohol, preventing the formation of scale, suppressing side reactions, producing the alcohol in a short time in high yield and selectivity and suitable for mass-production. SOLUTION: A fluorine-containing alcohol expressed by general formula (2): Rf(A)OH (Rf is a 1-10C perfluoroalkyl group; and A is a 3-10C straight or branched-chain saturated hydrocarbon group) is produced by reacting a fluorine-containing alkyl halide expressed by general formula (1); Rf(A)X (X is a halogen atom) with an alkali metal 4-hydroxybutyrate using γ-butyrolactone as a solvent while keeping the reaction temperature to 90-130°C.