15251-37-3Relevant academic research and scientific papers
ELECTRON-ATTRACTING PROPERTIES OF FUNCTIONALIZED TRINITROBENZENES: SPECTROSCOPIC AND CALORIMETRIC STUDY OF CRYSTALLINE COMPLEXES WITH POLYNUCLEAR AROMATIC HYDROCARBONS
Casellato, Fulvia,Mascherpa, Achille,Turrio, Luigi,Girelli, Alberto
, p. 587 - 592 (2007/10/02)
The variation of the electron-accepting capability of functionalized trinitrobenzenes with changing functional group has been studied.The formation of charge-transfer complexes with polynuclear aromatic hydrocarbons appears to be affected more by steric hindrance of the functional groups than by their electron-withdrawing properties.The CT values of substituted trinitrobenzene-polynuclear aromatic hydrocarbon complexes is neither correlable with the electronic properties of functional groups nor with the Hammett ?p parameter.
