152589-48-5Relevant academic research and scientific papers
Stereoselective Construction of Quaternary Centres at Ambient Temperature by the Highly Stereocontrolled Migration of Groups Containing sp-, sp2-, and sp3-Hybridized Carbon Atoms
Marson, Charles M.,Walker, Andrew J.,Pickering, Jane,Hobson, Adrian D.,Wrigglesworth, Roger,Edge, Simon J.
, p. 5944 - 5951 (2007/10/02)
A very highly diastereoselective semipinacol rearrangement of 2,3-epoxy alcohols mediated by tin(IV) chloride at ambient temperatures is shown to be applicable to a wide variety of migration groups including methyl, tert-butyl, cyclopropyl, vinyl, alkynyl
