1527494-35-4

Basic information

• Product Name: 1-(4-(tert-butyl)phenoxy)-2-iodobenzene
• Synonyms: 1-(4-(tert-butyl)phenoxy)-2-iodobenzene
• CAS NO: 1527494-35-4
• Molecular Weight: 352.215
• Mol File: 1527494-35-4.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: 1-(4-(tert-butyl)phenoxy)-2-iodobenzene(CAS DataBase Reference)
• NIST Chemistry Reference: 1-(4-(tert-butyl)phenoxy)-2-iodobenzene(1527494-35-4)
• EPA Substance Registry System: 1-(4-(tert-butyl)phenoxy)-2-iodobenzene(1527494-35-4)

Safety Data

• Hazardous Substances Data: 1527494-35-4(Hazardous Substances Data)

Upstream product

• 3169-73-1 4-tert-butyl-1-(2-aminophenoxy)benzene 
• 3169-72-0 1-(4-(tert-butyl)phenoxy)-2-nitrobenzene 
• 1493-27-2 ortho-nitrofluorobenzene 
• 98-54-4 para-tert-butylphenol 

Downstream Products

• 1527494-49-0 N-(2-bromo-4-fluorophenyl)-N-(3-(2-(4-tert-butylphenoxy)phenyl)prop-2-yn-1-yl)acetamide 

Relevant articles and documents

A Fast Way to Fluorescence: A Fourfold Domino Reaction to Condensed Polycyclic Compounds

A fast and efficient palladium-catalyzed fourfold domino Sonogashira/double-carbopalladation/C H-activation reaction that converts simple aromatic systems into complex polycyclic hydrocarbons has been developed. A number of substituted products has thus been prepared in yields up to 89 %. The structural assignment has been confirmed by using single-crystal X-ray crystallography. The products show intriguing fluorescence activity and thus might serve as chemical sensors or fluorescent imaging dyes.

Four- and Sixfold Tandem-Domino Reactions Leading to Dimeric Tetrasubstituted Alkenes Suitable as Molecular Switches

A highly efficient palladium-catalyzed fourfold tandem-domino reaction consisting of two carbopalladation and two C-H-activation steps was developed for the synthesis of two types of tetrasubstituted alkenes 3 and 6 with intrinsic helical chirality starting from substrates 1 and 4, respectively. A sixfold tandem-domino reaction was also developed by including a Sonogashira reaction. 20 compounds with different substitution patterns were prepared with yields of up to 97%. Structure elucidation by X-ray crystallography confirmed helical chirality of the two alkene moieties. Photophysical investigations of some of the compounds showed pronounced switching properties through light-controlled changes of their stereochemical configuration.