15277-97-1

Basic information

• Product Name: TRIETHANOLAMINE BORATE
• Synonyms: 2’,2’’-nitrilotris[ethanolato]](3-)-n,o,o’,o’’]-[[(beta-4)-boro;Boric acid, cyclic nitrilotriethylene ester;Boron, [[2,2',2''-nitrilotris[ethanolato]](3-)-N,O,O',O'']-, (T-4)-;2,2',2''-NITRILOTRIETHANOL BORATE;2,2',2''-NITRILOTRIETHYL BORATE;BORATRANE;TRIS(HYDROXYETHYL)AMINE BORATE;TRIHYDROXYTRIETHYLAMINE BORATE
• CAS NO: 15277-97-1
• Molecular Formula: C₆H₁₂BNO₃
• Molecular Weight: 156.98
• EINECS: 206-003-5
• Mol File: 15277-97-1.mol
• Article Data: 3

Chemical Properties

• Melting Point: 235-237 °C(lit.)
• Boiling Point: 149.6 °C at 760 mmHg
• Flash Point: 44.3 °C
• Appearance: /solid
• Density: 1.13 g/cm³
• Storage Temp.: Store at RT.
• CAS DataBase Reference: TRIETHANOLAMINE BORATE(CAS DataBase Reference)
• NIST Chemistry Reference: TRIETHANOLAMINE BORATE(15277-97-1)
• EPA Substance Registry System: TRIETHANOLAMINE BORATE(15277-97-1)

Safety Data

• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26-36/37
• WGK Germany: 3
• RTECS: YJ8968050
• F: 10-21
• TSCA: No
• Hazardous Substances Data: 15277-97-1(Hazardous Substances Data)

Usage

Chemical Properties

white to slightly yellow crystals or cryst. powder

InChI:InChI=1/C6H12BNO3/c1-4-9-7-10-5-2-8(1)3-6-11-7/h1-6H2

Upstream product

• 102-71-6 triethanolamine 
• 11113-50-1 boric acid 

Downstream Products

• 121-43-7 Trimethyl borate 
• 150-46-9 triethyl borate 
• 23908-48-7 2-methylsilatrane 
• 102-71-6 triethanolamine 

Relevant articles and documents

COMPOSITIONS AND METHODS FOR REDUCTION OF KETONES, ALDEHYDES AND IMINIUMS, AND PRODUCTS PRODUCED THEREBY

A method of producing an alcohol, comprises reducing an aldehyde or a ketone with a hydridosilatrane. The reducing is carried out with an activator.

Organoboranes. LI. Convenient procedures for the recovery of pinanediol in asymmetric synthesis via one-carbon homologation of boronic esters

Matteson's asymmetric synthesis via a one-carbon homologation of the pinanediol boronic esters with (dichloromethyl)litihium at -100 deg C results in the insertion of a chloromethyl group into the carbon-carbon bond with > 99percent diastereoselectivity.This procedure makes possible the asymmetric synthesis of the chiral moiety, RR'CH*B(OR'')2, providing an alternative route to chiral hydroboration for these valuable chiral intermediates.Unfortunately, this method suffers from the remarkable difficulty encountered in the recovery of the pinanediol chiral auxiliary, making this asymmetric synthesis impractical.Fortunately, a systematic study of the problem has uncovered convenient procedures for the recovery of pinanediol from pianendiol boronate esters