152770-45-1

Basic information

• Product Name: N-methoxycarbonyl-N'-<1-acetonyl-2-nitro-2-(2-nitrophenylhydrazono)>ethyl-O-methylisourea
• CAS NO: 152770-45-1
• Molecular Weight: 410.343
• Mol File: 152770-45-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: N-methoxycarbonyl-N'-<1-acetonyl-2-nitro-2-(2-nitrophenylhydrazono)>ethyl-O-methylisourea(CAS DataBase Reference)
• NIST Chemistry Reference: N-methoxycarbonyl-N'-<1-acetonyl-2-nitro-2-(2-nitrophenylhydrazono)>ethyl-O-methylisourea(152770-45-1)
• EPA Substance Registry System: N-methoxycarbonyl-N'-<1-acetonyl-2-nitro-2-(2-nitrophenylhydrazono)>ethyl-O-methylisourea(152770-45-1)

Safety Data

• Hazardous Substances Data: 152770-45-1(Hazardous Substances Data)

Upstream product

• 365-33-3 2-nitrobenzenediazonium tetrafluoroborate 
• 132658-17-4 2,6-dimethoxy-5-nitro-4H-4-acetonylpyrimidine potassium salt 

Relevant articles and documents

SIGMA-COMPLEXES IN THE PYRIMIDINE SERIES. 11. 5-ARYLAZO-5-NITRO-2,5- AND -4,5-DIHYDROPYRIMIDINES FROM ANIONIC SIGMA COMPLEXES OF 5-NITROPYRIMIDINE

We have studied the reaction of acetonyl anionic sigma complexes of 5-nitropyrimidines with aryldiazonium salts. We have established that, independently of the position of the geminal unit in the sigma complex, electrophilic attack by the diazonium ion occurs at the C(5) atom with formation of 5-arylazo-5-nitro-2,5- and -4,5-dihydropyrimidines. The latter are unstable and upon isolation are converted to N-methoxycarbonyl-N'-(1-acetonyl-2-nitro-2-arylhydrazono)ethyl-O-methylisourea. The structure of one of these compounds has been proven by x-ray diffraction. Under alkaline conditions, aromatization of 2,5-dihydropyrimidines to 5-arylazo-2-acetonylpyrimidines occurs.