152836-53-8Relevant academic research and scientific papers
An easy synthesis of chiral sulfinyl allylic bromides and their use in the preparation of (R)(S)- and (S)(S)-2-p-tolylsulfinyl-1,3-alkadienes
Bonfand,Gosselin,Maignan
, p. 1667 - 1676 (2007/10/02)
Condensation of (R)-vinyl-o-tolylsulfoxide anion on carbonyl compounds led directly to chiral allylic sulfinylalcohols 1. By treatment with NBS/Me2S, these alcohols 1 were converted into the rearranged primary allylic bromides 2 via SN2/s
