153092-80-9Relevant academic research and scientific papers
Synthesis, Structure, and Rearrangement of Chlorobis(2,4,6-tri-tert-butylphenyl)gallane
Meller, Anton,Pusch, Stefan,Pohl, Ehmke,Haeming, Ludger,Herbst-Irmer, Regine
, p. 2255 - 2258 (2007/10/02)
The title compound 1 is easily obtained from GaCl3 and 2 equivalents of supermesityllithium.According to an X-ray structure analysis one of the supermesityl rings shows a large deviation from planarity.Heating of 1 in vacuo gives mainly two products: an isomer of 1 in which one of the supermesityl groups is bound to Ga by one of its tert-butyl groups (2) and a benzogallolane (3) formed by elimination of HCl, X-ray structure analyses and full NMR (1H, 13C) data are provided for 1 and 2, MS and characteristic NMR (1H, 13C) data for 3. - Key Words: Gallane, chlorobis(supermesityl)/ Rearrangement
