153114-19-3Relevant articles and documents
Synthesis and characterization of oligonuclear Ru, Co and Cu oxidation catalysts
Lee, Bao-Lin,Kaerkaes, Markus D.,Johnston, Eric V.,Inge, Andrew K.,Tran, Lien-Hoa,Xu, Yunhua,Hansson, Oerjan,Zou, Xiaodong,Akermark, Bjoern
, p. 5462 - 5470 (2010)
In this work, we report the preparation and crystal structures of three new oligonuclear complexes, Ru2(bbpmp)(μ-OAc)3 (4), [Co2(bbpmp)(μ-OAc)(μ-OMe)](PF6) (5), [Cu 4(Hbbpmp)2(μ-OAc)(H2O)2](OAc)(PF 6)2 (6) {H3bbpmp = 2,6-bis[(2-hydroxybenzyl)- (2-pyridylmethyl)aminomethyl]-4-methyl-phenol (3)}. The structures of the complexes were determined by single-crystal X-ray diffraction. The oxidation states of ruthenium, cobalt and copper in the complexes are +3, +3 and +2, respectively. In 4 and 5, RuIII and CoIII are coordinated to four oxygen and two nitrogen atoms in an octahedral geometry, while in 6, CuII adopts both octahedral (CuN2O4) and square-pyramidal (CuN2O3) geometry. The potential of the three complexes as oxidation catalysts has been investigated. Copyright
Phenol oxygen bridged binuclear copper (II) complex, and preparation and application of phenol oxygen bridged binuclear copper (II) complex
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Paragraph 0060-0063, (2018/11/22)
The invention relates to a phenol oxygen bridged binuclear copper (II) complex, and preparation and application of the phenol oxygen bridged binuclear copper (II) complex. Efficient antitumor effectscan be realized by the phenol oxygen bridged binuclear c