15317-78-9

Basic information

• Product Name: Nickel diisobutyldithiocarbamate
• Synonyms: NICKEL DI-ISO-BUTYDITHIOCARBAMATE;nickel diisobutyldithiocarbamate;bis(diisobutyldithio-carbamate)nickel;Nickel, bis[bis(2-methylpropyl)carbamodithioato-S,S']-, (SP-4-1)-;s’]-bis[bis(2-methylpropyl)carbamodithioato-(sp-4-1)-nicke;Bis(diisobutyldithiocarbamato)nickel;ISOBUTYL NICLATE;Nickel-Di-Isobutyldithiocarbamate(Ndibc)
• CAS NO: 15317-78-9
• Molecular Formula: C18H36N2NiS4
• Molecular Weight: 467.45
• EINECS: 239-354-8
• Product Categories: Organometallics
• Mol File: 15317-78-9.mol
• Article Data: 1

Chemical Properties

• Boiling Point: 441.63°C (rough estimate)
• Flash Point: 103.2 °C
• Appearance: COA
• Density: 1.27 Mg/m3 at 25oC (77°F)
• Vapor Pressure: 0.0262mmHg at 25°C
• CAS DataBase Reference: Nickel diisobutyldithiocarbamate(CAS DataBase Reference)
• NIST Chemistry Reference: Nickel diisobutyldithiocarbamate(15317-78-9)
• EPA Substance Registry System: Nickel diisobutyldithiocarbamate(15317-78-9)

Safety Data

• Hazardous Substances Data: 15317-78-9(Hazardous Substances Data)

Usage

General Description

Nickel diisobutyldithiocarbamate is a complex, organosulfur compound that is typically used as a raw material in the production of lubricant additives and rubber products. This chemical compound, developed from nickel salts and Dithiocarbamic acid, exhibits anti-oxidative properties, potentially improving the durability of the materials to which it is applied. Nevertheless, it is considered potentially hazardous, known for being harmful if swallowed or inhaled, and may cause damage to the respiratory tract. Also, it is known to have adverse ecological effects due to its persistency and bioaccumulation potential. Hence, it requires careful handling and protective measures to be taken during both transport and operation.

InChI:InChI=1/2C9H19NS2.Ni/c2*1-7(2)5-10(9(11)12)6-8(3)4;/h2*7-8H,5-6H2,1-4H3,(H,11,12);/q;;+2/p-2

Upstream product

• 14701-22-5 nickel(II) 
• 2219-18-3 diisobutylcarbodithioic acid sodium salt 
• 83202-05-5 Ni(((CH₃)2CHCH₂)2NCS₂)3⁽¹⁺⁾*Br^(1-) = [Ni(((CH₃)2CHCH₂)2NCS₂)3]Br 

Relevant articles and documents

Structural organization of nickel(II), zinc(II), and copper(II) complexes with diisobutyldithiocarbamate: EPR, 13C and 15N CP/MAS NMR, and X-ray diffraction studies

The structures and spectroscopic properties of nickel(II), zinc(II), and copper(II) complexes with dibutyl- and diisobutyldithiocarbamate were studied by EPR and 13C and 15N CP/MAS NMR spectroscopy and X-ray diffraction analysis. According to the EPR data, copper(II) forms mononuclear [63/65Cu{S2CNR2}2] and heterobinuclear complexes [63/65CuZn{S2CNR 2}4] under magnetic dilution conditions. The isomeric forms of nickel(II) and zinc(II) diisobutyldithiocarbamates were detected by 13C and 15N NMR spectroscopy. The crystalline zinc(II) diisobutyldithiocarbamate was found to have a unique structural organization with alternating mononuclear [Zn{S2CN(i-C4H 9)2}2] and binuclear molecular forms [Zn 2{ S2CN(i-C4H9)2} 4] in the 1 : 1 ratio.