153195-09-6Relevant articles and documents
Iridium as a general catalyst for the decarbonylative addition of aldehydes to alkynes
Wang, Jun,Guo, Xiangyu,Li, Chao-Jun
supporting information; experimental part, p. 211 - 215 (2011/02/17)
A general catalytic system for the decarbonylative addition reaction of aldehydes with alkynes is developed by using an iridium catalyst system. Both aromatic and aliphatic aldehydes reacted with terminal alkynes efficiently to give the corresponding olefination products in high yields and up to 11:1 E/Z selectivity.
Suzuki-Miyaura cross-coupling reactions of potassium alkenyltrifluoroborates
Molander, Gary A.,Bernardi, Carmem R.
, p. 8424 - 8429 (2007/10/03)
We have previously reported that the palladium-catalyzed cross-coupling reaction of air-stable potassium alkenyltrifluoroborates with aryl halides and triflates proceeds readily with good yields. Recent progress in outlining the scope and limitations of s