153226-63-2

Upstream product

• 153226-64-3 methyl 3,4-O-(2,2,2-trichloroethylidene)-α-D-altropyranoside 
• 153226-59-6 Methyl-2,6-Di-O-benzoyl-3,4-O-(2,2,2-trichlorethyliden)-α-D-altropyranosylfluorid 

Relevant academic research and scientific papers

Rearrangement of Carbohydrate Epoxides to Acetals Using a Hemiacetal Neighbouring Group

When glycosides containing an epoxide functionality are treated with a nonenolisable aldehyde and sodium hydride, the free hydroxy groups are converted into hemiacetal salts, which subsequently open the epoxide ring to give sugar acetals.The reaction was