153258-85-6

Basic information

• Product Name: [(4-Bromo-phenyl)-methoxycarbonylmethylsulfanyl-methylsulfanyl]-acetic acid methyl ester
• Synonyms: [(4-Bromo-phenyl)-methoxycarbonylmethylsulfanyl-methylsulfanyl]-acetic acid methyl ester
• CAS NO: 153258-85-6
• Molecular Weight: 379.296
• Mol File: 153258-85-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: [(4-Bromo-phenyl)-methoxycarbonylmethylsulfanyl-methylsulfanyl]-acetic acid methyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: [(4-Bromo-phenyl)-methoxycarbonylmethylsulfanyl-methylsulfanyl]-acetic acid methyl ester(153258-85-6)
• EPA Substance Registry System: [(4-Bromo-phenyl)-methoxycarbonylmethylsulfanyl-methylsulfanyl]-acetic acid methyl ester(153258-85-6)

Safety Data

• Hazardous Substances Data: 153258-85-6(Hazardous Substances Data)

Upstream product

• 1122-91-4 4-bromo-benzaldehyde 

Downstream Products

• 1122-91-4 4-bromo-benzaldehyde 
• 505-73-7 disulfanediyldiacetic acid 
• 586-76-5 4-Bromobenzoic acid 

Relevant articles and documents

SYNTHESIS, SPECTRAL STUDIES AND C-S BOND FISSION THROUGH PUMMERER REACTION OF SOME ALKYLDIACETATES

A series of methyl and ethyldiacetates have been synthesized and their structures were identified.Correlation between δ-values of the benzylidene protons and ?-Hammett values has been found.The internal chemical shift Δν of the methylene protons was found to be correlated linearly with ?-Hammett constants indicating that the sulfur atom could transmit a polar effect to the substituent.Studies of H2O2 oxidation suggested that a competition between Pummerer and elimination reactions of the intermediate was involved. Key words: Benzylidene dithio diacetates; (1)HNMR spectra; Pummerer reaction