153307-55-2Relevant academic research and scientific papers
Selective Synthesis of the Geometrical Isomers of O,O-Diethyl O-1-(N-methoxyimino)ethylphosphorothioate and a New Thiono-Thiolo Rearrangement Reaction
Sasaki, Mitsuru,Itoh, Yoshikazu,Yamamoto, Noboru,Yamada, Yoshimi
, p. 1835 - 1838 (2007/10/02)
Condensation of O,O-diethyl phosphorochloridothioate with N-methoxyacetamide in the presence of a base gave selectively the geometrical isomers of O,O-diethyl O-1-(N-methoxyimino)ethylphosphorothioate which on heating rearranged to the corresponding thiolo isomers having P-S-C=N linkage.
