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CAS

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153379-66-9

(1S,6S,8aS)-6-(benzyloxycarbonylamino)octahydroindolizin-1-yl acetate is a chemical with a specific purpose. Lookchem provides you with multiple data and supplier information of this chemical.

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  • 153379-66-9 Structure

  • Basic information

    1. Product Name: (1S,6S,8aS)-6-(benzyloxycarbonylamino)octahydroindolizin-1-yl acetate
    2. Synonyms: (1S,6S,8aS)-6-(benzyloxycarbonylamino)octahydroindolizin-1-yl acetate
    3. CAS NO:153379-66-9
    4. Molecular Formula:
    5. Molecular Weight: 332.4
    6. EINECS: N/A
    7. Product Categories: N/A
    8. Mol File: 153379-66-9.mol

  • Chemical Properties

    1. Melting Point: N/A
    2. Boiling Point: N/A
    3. Flash Point: N/A
    4. Appearance: N/A
    5. Density: N/A
    6. Refractive Index: N/A
    7. Storage Temp.: N/A
    8. Solubility: N/A
    9. CAS DataBase Reference: (1S,6S,8aS)-6-(benzyloxycarbonylamino)octahydroindolizin-1-yl acetate(CAS DataBase Reference)
    10. NIST Chemistry Reference: (1S,6S,8aS)-6-(benzyloxycarbonylamino)octahydroindolizin-1-yl acetate(153379-66-9)
    11. EPA Substance Registry System: (1S,6S,8aS)-6-(benzyloxycarbonylamino)octahydroindolizin-1-yl acetate(153379-66-9)

  • Safety Data

    1. Hazard Codes: N/A
    2. Statements: N/A
    3. Safety Statements: N/A
    4. WGK Germany:
    5. RTECS:
    6. HazardClass: N/A
    7. PackingGroup: N/A
    8. Hazardous Substances Data: 153379-66-9(Hazardous Substances Data)

153379-66-9 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 153379-66-9 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 1,5,3,3,7 and 9 respectively; the second part has 2 digits, 6 and 6 respectively.
Calculate Digit Verification of CAS Registry Number 153379-66:
(8*1)+(7*5)+(6*3)+(5*3)+(4*7)+(3*9)+(2*6)+(1*6)=149
149 % 10 = 9
So 153379-66-9 is a valid CAS Registry Number.

153379-66-9Relevant articles and documents

Highly Enantioselective Approach to Indolizidines: Preparation of (+)-(1S,8aS)-1-Hydroxyindolizidine and (-)-Slaframine

Pourashraf, Mehrnaz,Delair, Philippe,Rasmussen, Martin O.,Greene, Andrew E.

, p. 6966 - 6972 (2007/10/03)

A highly stereoselective approach to (-)-slaframine and its probable biosynthetic precursor (+)-(1S,8aS)-1-hydroxyindolizidine has been developed based on a diastereofacially selective cycloaddition of dichloroketene with a chiral dienol ether.

Total synthesis of (-)-slaframine from (2R,3S)-3-hydroxyproline

Knight, David W.,Sibley, A. William

, p. 2179 - 2187 (2007/10/03)

The yeast reduction products (2R,3S)-N-Boc-3-hydroxyproline esters 23 have been converted into the 3-methoxymethoxyprolinal 26 which undergoes an efficient Julia olefination with the L-serine-derived amino sulfone 29. Selective reduction of the resulting alkene 31 using diimide and cyclization leads to N-(benzyloxycarbonyl)slaframine 33c and thence to natural (-)-slaframine 5 and its more stable, crystalline N-acetyl derivative 34.

A total synthesis of (-)-slaframine from (+)-cis-(2R,3S)-3-hydroxyproline

Knight,Sibley

, p. 6607 - 6610 (2007/10/02)

A total synthesis of the naturally occurring indolizidine (-)-Slaframine 4 has been achieved, starting from the cis-3-hydroxyproline derivative 1, in which a key step is a Julia olefination reaction using the dianion derived from the β-aminosulfone 5.

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