153457-05-7

Basic information

• Product Name: 1-Propanone, 1-(4-bromophenyl)-, oxime
• Synonyms: 1-Propanone,1-(4-bromophenyl)-,oxime;1-(4-bromo-phenyl)-propanone oxime
• CAS NO: 153457-05-7
• Molecular Formula: C9H10BrNO
• Molecular Weight: 228.088
• Mol File: 153457-05-7.mol
• Article Data: 4

Chemical Properties

• Boiling Point: 308.0±25.0 °C(Predicted)
• Density: 1.40±0.1 g/cm3(Predicted)
• CAS DataBase Reference: 1-Propanone, 1-(4-bromophenyl)-, oxime(CAS DataBase Reference)
• NIST Chemistry Reference: 1-Propanone, 1-(4-bromophenyl)-, oxime(153457-05-7)
• EPA Substance Registry System: 1-Propanone, 1-(4-bromophenyl)-, oxime(153457-05-7)

Safety Data

• Hazardous Substances Data: 153457-05-7(Hazardous Substances Data)

Upstream product

• 10342-83-3 4'-Bromopropiophenone 

Downstream Products

• 249915-91-1 4-(4-bromo-phenyl)-5-methyl-2-(4-trifluoromethyl-phenyl)-oxazole 
• 874150-51-3 C₁₈H₁₅Br₂N 
• 1108684-03-2 (S)-1-(p-bromophenyl)propan-1-amine 
• 1108684-03-2 (R)-1-(p-bromophenyl)propan-1-amine 
• 10342-83-3 4'-Bromopropiophenone 
• 4489-22-9 (S)-1-(4-bromophenyl)propan-1-ol 
• 4489-22-9 (R)-1-(4-bromophenyl)propanol 
• 1225220-08-5 (Z)-N-(1-(4-bromophenyl)prop-1-enyl)acetamide 
• 249915-83-1 2-{3,5-dibromo-4'-[5-methyl-2-(4-trifluoromethyl-phenyl)-oxazol-4-yl]-biphenyl-4-yloxy}-3-phenyl-propionic acid methyl ester 
• 249915-94-4 2-{4'-[5-methyl-2-(4-trifluoromethyl-phenyl)-oxazol-4-yl]-biphenyl-4-yloxy}-3-phenyl-propionic acid methyl ester 
• 1026798-58-2 {3,5-dibromo-4'-[5-methyl-2-(4-trifluoromethyl-phenyl)-oxazol-4-yl]-biphenyl-4-yloxy}-acetic acid methyl ester 
• 249915-81-9 3,5-dibromo-4'-[5-methyl-2-(4-trifluoromethyl-phenyl)-oxazol-4-yl]-biphenyl-4-ol 
• 249915-92-2 {4'-[5-methyl-2-(4-trifluoromethyl-phenyl)-oxazol-4-yl]-biphenyl-4-yloxy}-acetic acid methyl ester 

Relevant articles and documents

Elemental tellurium mediated synthesis of 2-(trifluoromethyl)oxazoles using trifluoroacetic anhydride as reagent

An elemental tellurium mediated synthesis of 2-(trifluoromethyl)oxazoles from the reaction of acetophenone oxime acetates with trifluoroacetic anhydride has been developed. This new tandem cyclization proceeds in good to excellent yields via a SET reduction followed by a 5-endo-trig pathway. Some of the title compounds showed fungicidal and insecticidal activities.

N, N′-dioxide-Cu(OTf)2 complex catalyzed highly enantioselective amination reaction of N-acetyl enamide

The N,N′-dioxide-Cu(OTf)2 complexes were applied in the asymmetric amination reaction of N-acetyl enamides with dialkyl azodicarboxylate, giving the corresponding products in good yields with high enantioselectivities (up to 91% ee). Precursors of vicinal diamine were readily obtained with excellent diastereoselectivities (>95:5) by NaBH4 reduction.