153477-75-9Relevant academic research and scientific papers
New Organophosphorus Ligands: 1,1,2-Tris(diphenylphosphanyl)cyclopropane and Its Derivatives
Schmidbaur, Hubert,Manhart, Stefan,Schier, Annette
, p. 2259 - 2262 (2007/10/02)
Cyclopropanation of 1,1,2-tris(diphenylphosphanyl)ethene with dimethylsulfonium methylide affords the title compound 1.The trifunctional phosphane is transformed into the trioxide 2 and trisulfide 3 by oxidation with hydrogen peroxide or elemental sulfur, respectively.With the tetrahydrofuran-borane complex the tris(phosphane-borane) 4 is obtained.The crystal structure of compound 1 has been determined by single-crystal X-ray diffraction.Key Words: Cyclopropane, phosphanyl-substituted/ Phosphane ligands/ Phosphane oxide and sulfide/ Phosphane-borane
