153482-11-2

Upstream product

• 58871-10-6 3,4-di-O-benzyl-D-glucal 
• 74372-90-0 3,4,6-tri-O-benzyl-D-glucal epoxide 

Downstream Products

• 1053641-45-4 Acetic acid (2S,3R,4S,5R,6R)-4,5-bis-benzyloxy-6-benzyloxymethyl-2-((1S,3R,4R,5S,6R)-4,5-bis-benzyloxy-2,7-dioxa-bicyclo[4.1.0]hept-3-ylmethoxy)-tetrahydro-pyran-3-yl ester 

Relevant academic research and scientific papers

1,2-cis-α-Stereoselective Glycosylation Utilizing a Glycosyl-Acceptor-Derived Borinic Ester and Its Application to the Total Synthesis of Natural Glycosphingolipids

1,2-cis-α-Stereoselective glycosylations were conducted using a 1,2-anhydroglucose donor and mono-ol acceptors in the presence of a glycosyl-acceptor-derived borinic ester. Reactions proceeded smoothly under mild conditions to provide the corresponding α-

A note on the solid-phase synthesis of oligosaccharides by the Danishefski approach

The ZnCl2-mediated glycosidation of an α-1,2-epoxide, prepared by epoxidation of a glycal with 3,3-dimethyldioxirane, with an incoming glycal acceptor is not a priori, as advocated by Danishefski et al., a stereospecific process.