153498-52-3Relevant academic research and scientific papers
Novel Biradical Cyclization via Remote-Hydrogen Transfer in Photochemistry of 2-Dialylaminoethyl 3-Benzoylacrylates
Hasegawa, Tadashi,Yamazaki, Yuko,Yoshioka, Michikazu
, p. 3128 - 3131 (2007/10/02)
Upon irradiation, 2-(N,N-dibenzylamino)ethyl and 2-(N-benzyl-N-methylamino)ethyl 3-benzoylacrylate underwent photocyclization via remote-proton transfer from their (Z)-forms competing with (E)-(Z) isomerization. The quantum yield for the cyclization under the conditions where both (E)- and (Z)-isomers absorb the irradiation light was estimated to be 0.05 by applying the steady-state approximation.
