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• 100-51-6 benzyl alcohol 
• 10029-04-6 ethyl 2-(hydroxymethyl)acrylate 
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• 109240-66-6 2?(benzyloxymethyl)prop?2?en?1?ol 
• 347886-00-4 [2-(bromomethyl)prop-2-en-1-yloxy]methylbenzene 
• 237394-41-1 3-[(adamantan-1-yloxy)-(1-benzyloxycarbonylamino-2-phenyl-ethyl)-phosphinoyl]-2-benzyloxymethyl-propionic acid ethyl ester 
• 237394-54-6 3-[(adamantan-1-yloxy)-(1-benzyloxycarbonylamino-2-phenyl-ethyl)-phosphinoyl]-2-benzyloxymethyl-propionic acid 
• 237394-35-3 3-[(adamantan-1-yloxy)-(1-benzyloxycarbonylamino-ethyl)-phosphinoyl]-2-benzyloxymethyl-propionic acid ethyl ester 
• 237394-48-8 3-[(adamantan-1-yloxy)-(1-benzyloxycarbonylamino-ethyl)-phosphinoyl]-2-benzyloxymethyl-propionic acid 

Relevant academic research and scientific papers

Synthesis of 3-deoxy-2-uloses via the indium-mediated allylation reaction

Abstract: We utilized the indium-mediated allylation reaction for the synthesis of carbohydrate structures containing the 3-deoxy-2-ulose motif, a barely investigated compound class. The stereoselective outcome can be controlled by the presence or absence of a chelating group in α-position to the carbonyl function. By introduction of an UV-active allyl building block, we enabled epimer separation by HPLC towards the synthesis of 3-deoxy-d-glycero-d-galacto-2-nonulose, the carboxyl-reduced analogue of widely distributed 3-deoxy-d-glycero-d-galacto-nonulosonic acid (Kdn). Ozonolysis of the introduced 2-C-methylidenepropan-1-ol motif provided the desired 3-deoxy-2-uloses. Graphical abstract: [Figure not available: see fulltext.].