15359-12-3

Basic information

• Product Name: 3,6-dimethyl-2-cyclohexene-1-ol
• Synonyms: 3,6-dimethyl-2-cyclohexene-1-ol
• CAS NO: 15359-12-3
• Molecular Weight: 126.199
• Mol File: 15359-12-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 3,6-dimethyl-2-cyclohexene-1-ol(CAS DataBase Reference)
• NIST Chemistry Reference: 3,6-dimethyl-2-cyclohexene-1-ol(15359-12-3)
• EPA Substance Registry System: 3,6-dimethyl-2-cyclohexene-1-ol(15359-12-3)

Safety Data

• Hazardous Substances Data: 15359-12-3(Hazardous Substances Data)

Upstream product

• 15329-10-9 3,6-dimethylcyclohex-2-enone 

Downstream Products

• 3127-81-9 trans-2,5-dimethylcyclohexanol (1,2 trans) 
• 3127-81-9 (+/-)-1r,4c-Dimethyl-cyclohexanol-(2t) 
• 3127-81-9 (+/-)-1r,4c-Dimethyl-cyclohexanol-(2c) 
• 3127-81-9 trans-2,5-dimethylcyclohexanol (1,2 cis) 
• 113428-80-1 2-(1,4-dimethyl-2-cyclohexen-1-yl)-2-methylcyclopentanone 
• 109805-47-2 (+/-)-phenylcarbamic acid-(2t.5c-dimethyl-cyclohexyl-(r)-ester) 
• 109805-47-2 (+/-)-phenylcarbamic acid-(2t.5t-dimethyl-cyclohexyl-(r)-ester) 

Relevant articles and documents

Use of the Ketal Claisen Rearrangement for the Synthesis of Cyclic Sesquiterpenes Containing Quaternary Centers. A Formal Synthesis of Cuparene.

We have shown that the ketal based Claisen rearrangement can be useful for generating vicinal quaternary and tertiary-quaternary centers by suitable substitution on the reacting 2-cyclohexenols and cycloalkanone ketal.A rapid and efficient method for preparing hindered cycloalkanone ketals in very pure form is presented, as well as a useful modification for synthesizing the requied 2-cyclohexenols from alkyl anisoles with a minimum number of undesired side products.