153783-84-7

Basic information

• Product Name: Acetic acid, [[2-(4-methylphenyl)-2-oxoethyl]thio]-
• CAS NO: 153783-84-7
• Molecular Formula: C11H12O3S
• Molecular Weight: 224.28
• Mol File: 153783-84-7.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: Acetic acid, [[2-(4-methylphenyl)-2-oxoethyl]thio]-(CAS DataBase Reference)
• NIST Chemistry Reference: Acetic acid, [[2-(4-methylphenyl)-2-oxoethyl]thio]-(153783-84-7)
• EPA Substance Registry System: Acetic acid, [[2-(4-methylphenyl)-2-oxoethyl]thio]-(153783-84-7)

Safety Data

• Hazardous Substances Data: 153783-84-7(Hazardous Substances Data)

Upstream product

• 68-11-1 mercaptoacetic acid 
• 619-41-0 4-(bromoacetyl)toluene 
• 122-00-9 para-methylacetophenone 

Downstream Products

• 122-00-9 para-methylacetophenone 
• 153783-94-9 ethyl 2-((2-oxo-2-(p-tolyl)ethyl)thio)acetate 
• 153784-54-4 6-(4-Methyl-benzoyl)-1-oxo-3,5-diphenyl-1λ⁴-thiomorpholine-2-carboxylic acid ethyl ester 
• 153784-42-0 6-(4-Methyl-benzoyl)-3,5-diphenyl-thiomorpholine-2-carboxylic acid ethyl ester 
• 153784-36-2 6-(4-Methyl-benzoyl)-3,5-diphenyl-thiomorpholine-2-carboxylic acid methyl ester 
• 153784-48-6 6-(4-Methyl-benzoyl)-1-oxo-3,5-diphenyl-1λ⁴-thiomorpholine-2-carboxylic acid methyl ester 
• 153784-05-5 (Oxo-p-tolyl-ethanesulfonyl)-acetic acid ethyl ester 
• 153783-99-4 (Oxo-p-tolyl-ethanesulfonyl)-acetic acid methyl ester 
• 200577-00-0 (4-p-Tolyl-[1,2,3]selenadiazole-5-sulfonyl)-acetic acid 
• 200577-06-6 (2-p-Tolyl-ethynesulfonyl)-acetic acid 
• 200576-94-9 p-Tolylethynylsulfanyl-acetic acid 
• 158606-47-4 C₁₈H₁₈O₃S 
• 155782-70-0 C₁₇H₁₅ClO₂S 
• 98821-30-8 (E,E)-p-methylstyryl styryl sulfone 

Relevant articles and documents

An umpolung oxa-[2,3] sigmatropic rearrangement employing arynes for the synthesis of functionalized enol ethers

An oxa-[2,3] sigmatropic rearrangement involving arynes is reported featuring the umpolung of ketones, where the C=O bond polarity is reversed. The in situ-generated sulfur ylides from β-keto thioethers and arynes undergo efficient rearrangement allowing the facile and robust synthesis of functionalized enol ethers in high yields and excellent functional group compatibility. Preliminary mechanistic studies rule out the possibility of Pummerer-type rearrangement operating in this case.

Tetrahydro-1,4-thiazine-1,1-dioxides: Part IV - Synthesis and conformational analysis of some 2,3,5-trisubstituted tetrahydro-1,4-thiazine-1,1-dioxides

A series of new 2-aroyl-3,5-diaryltetrahydro-1,4-thiazine-1,1-dioxides (2) has been synthesized either from phenacylsulfonylacetic acids (1) or phenacylstyrylsulfones (3), which in turn are obtained from the substituted acetophenones or styrenes, respecti