153872-85-6Relevant academic research and scientific papers
2,4-Di-t-butyl-6-methoxyphenyldithioxophosphorane as a Probe for the Mechanistic Studies of Lawesson's Reagent
Yoshifuji, Masaaki,An, De-Lie,Toyota, Kozo,Yasunami, Masafumi
, p. 4379 - 4382 (1994)
The chemical conversion of carbonyl to thiocarbonyl compound was directly achieved by the treatment of benzophenone with 2,4-do-t-butyl-6-methoxyphenyldithioxophosphorane, which was prepared by the thermolysis of the corresponding dimeric species, 1,3,2,4-dithiadiphosphetane 2,4-disulfides.
New type of phosphorus compounds containing sulfur and selenium
Yoshifuji, Masaaki
, p. 557 - 560 (2007/10/03)
New type of phosphorus compounds containing the P=S or P=Se groups were prepared by utilization of sterically protecting group carrying amino groups with the aid of intramolecular coordination effect.
Preparations and Sulfurization Reactions of (2,4-Di-t-butyl-6-methoxyphenyl)phosphine and 1-(2,4-Di-t-butyl-6-methoxyphenyl)-2-(2,4,6-tri-t-butylphenyl)diphosphene
Yoshifuji, Masaaki,An, De-Lie,Toyota, Kozo,Yasunami, Masafumi
, p. 2069 - 2072 (2007/10/02)
A phosphonous dichloride carrying 2,4-di-t-butyl-6-methoxyphenyl as a novel sterically protecting group was prepared and converted to an unsymmetrical diphosphene, which reacted with sulfur to give the corresponding diphosphene sulfide and thiadiphosphira
