1539304-52-3Relevant academic research and scientific papers
Synthesis and properties of 172-phenyl-5,10,15,20- tetraazatribenzo[b,g,l]pyrazino[2,3-q]porphyrin-173(17 4H)-one
Malyasova,Kokareva,Tarakanov,Aleksandriiskii,Khelevina,Koifman
, p. 1812 - 1818 (2013)
172-Phenyl-5,10,15,20-tetraazatribenzo[b,g,l]pyrazino[2,3-q] porphyrin-173(174H)-one was synthesized for the first time by template cyclotetramerization of 5,7-diphenyl-6H-1,4-diazepine-2,3- dicarbonitrile with phthalonitrile. Its complexation with zinc(II) acetate followed a bimolecular mechanism. Acid-base properties of the resulting zinc complex in benzene-acetic acid were studied, and the stability constant of its monoprotonated (at the meso-nitrogen atom) form was determined.
