153933-73-4Relevant academic research and scientific papers
The Reaction of Nitrile Oxide with Organometallic Compounds
Kim, Jae Nyoung,Kim, Hyoung Rae,Ryu, Eung K.
, p. 5117 - 5120 (1993)
Nitrile oxides react with some organometallic compounds with or without the aid of Lewis acid depending on the organometallic nucleophiles to give oxime derivatives in good yields.
Novel BODIPY preparations from sterically hindered pyrroles. Synthesis and photophysical behavior in solution, polystyrene nanoparticles, and solid phase
Meallet-Renault,Clavier,Dumas-Verdes,Badre,Shmidt, E. Yu.,Mikhaleva,Laprent,Pansu,Audebert,Trofimov
, p. 2247 - 2256 (2008)
Trimesityl-BODIPY (TMB), a new derivative of 4,4-difluoro-4-bora-3a,4a- diaza-s-indacene belonging to fluores-cent nanostructures series, was synthesized from the corresponding pyrrole by the Trofimov reaction. This reaction was also employed to obtain 2-[2.2]paracyclophanylpyrrole from 5-acetyl[2.2]-paracyclophane. The spectral properties of TMB have been investigated in dichloromethane, nanolatex (polystyrene) films prepared by rapid solvent evaporation, and microcrystals. Comparative analysis of TMB properties with those of mesityl-BODIPY (MB) was performed. TMB was prepared to minimize π-π interactions in order to preserve luminescence in the aggregate state. Both fluorophores were shown to form fluorescing aggregates in the amorphous state (film). Fluorescence spectra (extinction and lifetime) were also studied. In crystal, MB shows a weaker fluorescence, while TMB behaves as a single fluorescing aggregate with a lifetime of 9.5 ns.
Aluminium chloride promoted carbohydroximoylation reaction of aromatic compounds with primary nitroalkanes
Kim,Song,Ryu
, p. 1711 - 1715 (2007/10/02)
The reaction of primary nitroalkanes with aromatic compounds in the presence of aluminium chloride afforded the corresponding carbohydroximoylated aromatic compounds.
